• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Material for construction by molding, extrusion or 3D printing. The present invention relates to a material for construction comprising: - at least between 0.1-6.9% by weight of vegetable straw, - 0.1-25% by weight of carboxymethylcellulose (CMC), methylcellulose (MC) or a combination of both, 0.1-12% by weight of natural polysaccharide selected from the group consisting of D-galactose, L-arabinose, L-rhamnose, D-glucuronic acid, natural gums and combinations thereof, preferably gum arabic or gum tragacanth, - water, at least between 0.1 and 45% by weight, where all the percentages are percentages by weight with respect to the total weight of the construction material, and its use in molding, extrusion or 3D printing, particularly preferred for the manufacture of furniture or monuments falleros. (Machine-translation by Google Translate, not legally binding)
    公开号:ES2703455A1
    申请号:ES201731095
    申请日:2017-09-21
    公开日:2019-03-08
    发明作者:Ibanez José Ramón Albiol；Barbera Javier Mas；Lopez Miguel Sanchez；Cuesta Rubén Tortosa
    申请人:Universidad Politecnica de Valencia；
    IPC主号:
    专利说明:

    [0001]
    [0002]
    [0003]
    [0004] Field of the invention
    [0005]
    [0006] The present invention is part of the field of construction materials, in particular for furniture manufacture, fallas monuments, packaging material, among others.
    [0007]
    [0008] BACKGROUND OF THE INVENTION
    [0009]
    [0010] Document CA2831629A1 refers to an element for construction from natural waste compounds (rice straw, wood sawdust, among others), a binder and water. The proportion in which these components are present is between 80-85% by weight of the natural waste compounds, 2-5% by weight of the paper pulp binder and 10-18% by weight of water. Both the rice straw and the wood sawdust are crushed and milled to obtain a grain size of between 0.5-2mm. The mixture after its stirring is molded under pressure for 30-45 seconds and at a temperature between 130-160 ° C. The product described in CA2831629 discloses a construction material made of rice straw and other materials of plant origin with a particle size of 0.5-2 mm, but does not comprise the components of the material of the present invention in the proportions that are required and The obtaining procedure requires high temperatures of 130-160 ° C that make it a more expensive and less environmentally friendly product.
    [0011]
    [0012] Document CN101152727A discloses a board for decorative purposes from agricultural straw and / or wood sawdust (65-75%), carboxymethylcellulose (5-8%) as adhesive-binder and water (10-20%) as components majority Once the components are mixed, they can be formed manually or in a machine under pressure. The product described does not comprise the components of the material of the present invention in the proportions that are required, but in addition it requires a drying temperature of between 60 and 100 ° C and would not be suitable for 3D printing.
    [0013] US2015354143A1 discloses a board made from rice straw, wood sawdust between 0.2-5mm particle size, a natural polysaccharide arabinose or galactose and a resin type adhesive of polyvinylacetate, formaldehyde, melamine, or diisocyanate, among others . The product described does not comprise the components of the material of the present invention in the proportions that are required and the adhesives used are less respectful to the environment than the natural polysaccharide used in the present invention.
    [0014]
    [0015] Document CN104097246A refers to a panel containing rice straw (65-70%), wood sawdust (12.5-17.5%) and an adhesive (3.47-4.25%) of isocyanate type as main components. The products are mixed in an extruder and subsequently the plates are formed by molding at temperatures between 130-150 ° C. The product described does not comprise the components of the material of the present invention in the proportions that are required and the adhesives used are less respectful to the environment than the natural polysaccharide used in the present invention.
    [0016]
    [0017] Document CN106007617A discloses decorative panels formed from agricultural straw (50-70%), wood sawdust (20-25%), rice straw fiber (6-8%) and carboxymethylcellulose (3-5%) as main components. The product described does not comprise the components of the material of the present invention in the proportions that are required and also contains components such as 8% hydrochloric acid and pine tar, or zinc powder, which are not suitable for the environment.
    [0018]
    [0019] Document US2014053435A1 describes a device of identification labels for events, subject to textile garments, from rice straw and sawdust among others. The material is manufactured by injection molding.
    [0020]
    [0021] In view of the aforementioned state of the art, there is still a need for a material that, in addition to taking advantage of residues such as vegetable straw, is more respectful of the environment, both because of the nature of its components and because of its production procedure. In addition, there is a need for suitable materials for both the manufacturing of objects by both molding, extrusion, and 3D printing.
    [0022] The material of the present invention overcomes these drawbacks of the state of the art to be its components from the recycling and also non-toxic components, and not be necessary at any time the use of heat energy (furnaces) for its preparation. Thus, the energy saving in its production is greater.
    [0023]
    [0024] To these advantages associated with the materials used in the material of the invention and its method of obtaining, the fact of being a suitable material for 3D printing, and therefore suitable for new technologies, in addition to the materials mentioned in the previous documents.
    [0025]
    [0026] Description of the invention
    [0027]
    [0028] Throughout this report all percentages indicated, unless otherwise specified, are percentages by weight with respect to the total weight of the construction material.
    [0029]
    [0030] The present invention relates to a material for the construction by molding, extrusion and 3D printing, which we will call to simplify "material for construction".
    [0031]
    [0032] The present invention relates to a material as defined in claim 1 and to particular embodiments defined in the dependent claims.
    [0033]
    [0034] The present invention relates first of all to a construction material comprising:
    [0035] - at least between 0.1-6.9% by weight of vegetable straw,
    [0036] - 0.1-25% by weight of carboxymethylcellulose (CMC), methylcellulose (MC) or a combination of both, preferably 2-24%, and more preferably still 6 to 23% by weight of carboxymethylcellulose or methylcellulose, or a combination of both, - 0.1-12% by weight of natural polysaccharide selected from the group consisting of D-galactose, L-arabinose, L-rhamnose, D-glucuronic acid, natural gums - also referred to herein as organic resins - and combinations thereof, preferably gum arabic or gum tragacanth, preferably from 1 to 11%, and more preferably even from 2-10%,
    [0037] - water, at least between 0.1 and 45% by weight.
    [0038] According to particular embodiments, the vegetable straw is present in a percentage of 0.5-18%, or according to additional particular embodiments in a percentage comprised between 2-17% by weight.
    [0039]
    [0040] According to additional particular embodiments, the material may further comprise the following components:
    [0041] - at least 0.1-6.9% by weight of wood sawdust, so that wood sawdust and vegetable straw account for a maximum of 7% by weight,
    [0042] 0.1-25% by weight of propyl, isopropyl, ethyl alcohol, or combinations thereof, preferably 5-20%, and more preferably still 8-15% by weight of isopropyl and / or ethyl alcohol,
    [0043] 0.1-5% by weight of a weak acid, preferably 0.5-4%, and more preferably even 1-3% of weak acid.
    [0044]
    [0045] According to further particular embodiments, the wood sawdust is present in a percentage of between 0.1-3%, or according to additional particular embodiments in a percentage comprised between 0.1-2% by weight, so that the wood sawdust and vegetable straw account for a maximum of 7% by weight.
    [0046]
    [0047] According to further particular embodiments of the invention, the construction material comprises:
    [0048] - 0.1-17.9% by weight of vegetable straw,
    [0049] - 0.1-25% by weight of carboxymethylcellulose (CMC), methylcellulose (MC) or a combination of both,
    [0050] - 0.1-12% by weight of natural polysaccharide selected from the group consisting of D-galactose, L-arabinose, L-rhamnose, D-glucuronic acid, natural gums - also referred to herein as organic resins - and combinations thereof, preferably rubber gum arabic or gum tragacanth, preferably from 1 to 11%, and more preferably even from 2-10%,
    [0051] - 0.1-17.9% by weight of wood sawdust, so that wood sawdust and vegetable straw account for a maximum of 18% by weight,
    [0052] 0.1-25% by weight of propyl, isopropyl, ethyl alcohol, or combinations thereof, preferably 5-20%, and more preferably still 8-15% by weight of isopropyl and / or ethyl alcohol,
    [0053] 0.1-5% by weight of a weak acid, preferably 0.5-4%, and more preferably even 1-3% of weak acid,
    [0054] - water between at least 0.1 and 45% by weight.
    [0055]
    [0056] According to further particular embodiments of the invention, the construction material comprises:
    [0057] - 9-17.9% by weight of vegetable straw,
    [0058] - 0.1-9% by weight of wood sawdust, so that wood sawdust and vegetable straw account for a maximum of 18% by weight,
    [0059]
    [0060] According to a preferred embodiment of the invention, the construction material comprises:
    [0061] - 4-6.9% by weight of vegetable straw,
    [0062] - 0.1-3% by weight of wood sawdust, so that wood sawdust and vegetable straw account for a maximum of 7% by weight,
    [0063]
    [0064] According to additional particular embodiments, the material comprises:
    [0065] - 5-6.9% by weight of vegetable straw, so that wood sawdust and vegetable straw account for a maximum of 7% by weight,
    [0066] - 0.1-2% by weight of wood sawdust, preferably 0.5-7% and more preferably still 1-6% by weight of wood sawdust,
    [0067] - 0.1-25% by weight of carboxymethylcellulose (CMC), methylcellulose (MC) or a combination of both, preferably 2-24%, and more preferably still 6 to 23% by weight of carboxymethylcellulose (CMC), methylcellulose (MC) ) Or a combination of both,
    [0068] 0.1-12% by weight of gum arabic, preferably from 1 to 11%, and more preferably still from 2-10% by weight of gum arabic,
    [0069] - 0.1-25% by weight of isopropyl alcohol, ethyl, or combinations thereof, preferably 0.5-24%, and more preferably still 1-23% by weight, - 0.1-5% by weight of a weak acid, preferably 0.5-4% by weight, and more preferably even 1-3% weak acid,
    [0070] - water between at least 0.1 and 45% by weight.
    [0071]
    [0072] According to further preferred particular embodiments, the material comprises: - 14-17.9% by weight of rice straw
    [0073] 0.1-25% by weight of carboxymethylcellulose, methylcellulose or a combination of both
    [0074] - 0.1-10% by weight of gum arabic,
    [0075] - water between at least 0.1 and 45% by weight,
    [0076] - 0.1-4% by weight of wood sawdust, so that wood sawdust and rice straw account for a maximum of 18% by weight
    [0077] - 0.1-25% by weight of isopropyl alcohol, ethyl, or combinations thereof, - 0.1-5% by weight of a weak acid,
    [0078] where all the percentages are percentages by weight with respect to the total weight of the construction material.
    [0079]
    [0080] According to more preferred particular embodiments, the material comprises:
    [0081] - 5-6.9% by weight of rice straw, so that the wood sawdust and rice straw account for a maximum of 7% by weight,
    [0082] - 0.1-2% by weight of wood sawdust,
    [0083] - 0.1-25% by weight of carboxymethylcellulose (CMC), methylcellulose (MC) or a combination of both,
    [0084] - 0.1-12% by weight of gum arabic,
    [0085] - 0.1-25% by weight of isopropyl alcohol, ethyl, or combinations thereof, - 0.1-5% by weight of acetic acid,
    [0086] - water between at least 0.1 and 45% by weight.
    [0087]
    [0088] According to further more preferred particular embodiments, the material comprises: - 14-17.9% by weight of rice straw
    [0089] - 0.1-4% by weight of wood sawdust, so that wood sawdust and rice straw account for a maximum of 18% by weight
    [0090] 0.1-25% by weight of carboxymethylcellulose, methylcellulose or a combination of both
    [0091] - 0.1-10% by weight of gum arabic,
    [0092] - water between at least 0.1 and 45% by weight,
    [0093] - 0.1-25% by weight of isopropyl alcohol, ethyl, or combinations thereof, - 0.1-5% by weight of acetic acid,
    [0094] where all the percentages are percentages by weight with respect to the total weight of the construction material.
    [0095]
    [0096] Compositions of the material with a lower percentage of vegetable straw are more suitable for use in 3D printing.
    [0097]
    [0098] Among the woods that are useful according to the invention as raw material for the component called "wood sawdust", any type of wood (hard or soft) can be used in general, and in particular those that are known in the context of hardwood and coniferous trees , according to the building technical code (CTE), but preferably low density woods are used, such as raft, pine, poplar, willow, poplar, elm, cypress, fir, cedar or high density such as oak, beech, chestnut, walnut, teak, olive, mahogany, cherry, ash or combinations of them.The low density makes the resulting product weigh less.This issue is important to lighten the weight of the material in certain applications, for example, its use in the manufacture of "ninots" of the faults, where it is crucial that they are very light, and therefore, that the wood used is also very light.
    [0099]
    [0100] Among the vegetable straw, any type of vegetable straw, for example wheat straw, oats, rye, barley, rice or combinations thereof, preferably rice straw, are considered to be useful materials for the material of the present invention.
    [0101]
    [0102] Among the advantages of the material object of the invention it can be mentioned, for example, that, in the case of the use of rice straw, a reuse of this agricultural residue is achieved. For example, in the case of rice straw - very abundant in Mediterranean areas such as Levante - it is avoided that it burns in the rice fields and with its recycling in the material of the invention can be burned only, for example, in the Fallas monuments, also avoiding the burning of other toxic materials.
    [0103]
    [0104] Among the alcohols that can be used in the material of the invention are alcohols that are cheap and non-contaminating, such as propyl, isopropyl, ethyl, or combinations thereof, preferably isopropyl and ethyl.
    [0105] As the weak acid, for example, acetic, citric, boric, carbonic, phosphoric acid and mixtures thereof can be used. Preferably acetic acid is used for its cost and pertinent handling.
    [0106]
    [0107] The construction material of the invention can also comprise additives, for example, aerating agents, fluidizers, flame retardants, flame promoters, dyes, among others. The percentage of additives can be, for example, between 0.01 and 3% by weight of the material for construction, preferably 0.1-2% and more preferably 0.2-1%.
    [0108]
    [0109] According to a particular embodiment, some of the physical properties of the material of the present invention are the following:
    [0110]
    [0111] Average density: 0.67 gr / cm3
    [0112] Compression: average of 12.52 Kg / cm2
    [0113] Flexion: (Test of break to three points) average of 13.64 Kg / cm2
    [0114]
    [0115] The material of the invention is a paste, which can be preserved, wrapped, for example, in a polyethylene bag, the vacuum being made, and is available for use even 1 month after its manufacture. It can be stored at room temperature, without being exposed to sunlight.
    [0116]
    [0117] The CMC, or methylcellulose, by itself has little binding capacity and needs a subsequent heat treatment in furnace and pressure. However, in the material of the invention when joining it with the natural polysaccharide, it is possible to avoid this thermal treatment and pressure (energy and process savings) since the polysaccharide does have a great binding power.
    [0118] The polysaccharide alone does not have the workability and the proper viscosity to mold or print in 3D.
    [0119]
    [0120] The natural polysaccharide gives the final material the binding power during the process of molding, extrusion or 3D printing in which the material can be used, speed of drying and finally the resulting mechanical capacity after 48 hours have elapsed (which CMC can not provide ). Therefore, one of the advantages of the invention is that very good flow properties are achieved, viscosity, among others, in the material, thanks to the synergy between the CMC, or the methylcellulose, or its mixture, and the natural polysaccharide, preferably, gum arabic.
    [0121]
    [0122] Among the advantages of the material of the invention, it can be mentioned that it is a material that includes recycled components such as vegetal straw, ecological, combustible and biodegradable. They are also remarkable advantages that is a material that serves to work in molding, and specifically manual molding, extrusion and manufacturing in 3D printing.
    [0123]
    [0124] The present invention also relates to a process for the preparation of the material defined above.
    [0125]
    [0126] The present invention relates to a process for the preparation of the material as defined in the main claim of the process and to particular embodiments defined in the dependent claims.
    [0127]
    [0128] The process for the preparation of the material of the present invention comprises:
    [0129]
    [0130] - grinding and milling of the vegetable straw, preferably rice straw, obtaining a part A comprising vegetable straw
    [0131]
    [0132] - preparation of a part B, comprising at least
    [0133] - mix the carboxymethylcellulose, methylcellulose or a combination of both, with
    [0134] - the natural polysaccharide selected from D-galactose, L-arabinose, L-rhamnose, D-glucuronic acid and natural gums, or combinations thereof, preferably gum arabic or gum tragacanth,
    [0135] - And the water
    [0136] - mixing of part A and part B, resulting in the material of the invention ready for use.
    [0137]
    [0138] In the process for preparing the material of the invention it should be understood that the proportions in which each of the components of the material of the invention are found, are those that have been expressed in the definition of the material hereinabove.
    [0139] In the process of preparing the construction material, the mixing times and the speeds depend in all cases on the quantity of the components that are being mixed and the values indicated in this report are suitable values for laboratory scale quantities. Also these times and speeds depend on the power of the machine - blender - that is used.
    [0140]
    [0141] The mixing step of part A and part B can be carried out, for example, in a blender between 1 to 5 minutes at speeds, for example, such as 2,500 rpm.
    [0142]
    [0143] The preparation of part A may comprise according to particular embodiments:
    [0144]
    [0145] - grinding and milling of the vegetable straw, preferably rice straw, until a maximum particle size of up to 5 millimeters is obtained, preferably up to 3 millimeters (preferably for the use of the 3D printing material), or in the case of material for molding or extrusion, until obtaining fibers with a maximum length of up to 12 mm and a slenderness range between 40 and 70, preferably 10 mm in length and a slenderness range between 50-60. The fiber is characterized by its length and slenderness. Slenderness is defined as: Slenderness, e = L (mm) / D (microns).
    [0146]
    [0147] The preparation of part A may comprise according to additional particular embodiments:
    [0148] - crushing and grinding vegetable straw,
    [0149] - Selection of wood sawdust
    [0150] - mixed vegetable straw and wood sawdust.
    [0151]
    [0152] The preparation of part A may further comprise, according to additional particular embodiments:
    [0153] - addition of 0.1-20% by weight of propyl, isopropyl, ethyl alcohol, or combinations thereof.
    [0154]
    [0155] The preparation of part A may comprise according to additional particular embodiments:
    [0156] - grind and grind the vegetable straw up to specific particle sizes of up to 5 millimeters, preferably up to 3 millimeters maximum, or in the case of material for molding or extrusion, up to fibers of a length of up to 12 mm and a maximum slenderness range between 40 and 70, preferably 10 mm in length and a slenderness range between 50-60,
    [0157] - selection of wood sawdust with specific particle sizes of up to 5 millimeters maximum, preferably up to 3 millimeters maximum, or in the case of material for molding or extrusion, select fibers with a maximum length of up to 12 mm and a range of slenderness between 40 and 70, preferably 10 mm in length and a slenderness range between 50-60,
    [0158] - mixing the vegetable straw and the wood sawdust, for example, in a blender, at speeds, for example, of 2,500 rpm, for a time such as 1 minute,
    [0159] - adding propyl alcohol, isopropyl alcohol, ethyl alcohol or combinations of these, to the mixture obtained above and mixing, for example, in a blender, at speeds of, for example, 2,500 rpm, for a time that depends on the number of components that are present. mixing, and that can be, for example, 1 minute, or up to 10 minutes.
    [0160]
    [0161] Wood sawdust is used in the form of particles or fibers with specific granulometries that are selected according to the intended use of the construction material. These granulometries are a maximum of up to 5 mm, preferably a maximum of up to 3 mm for use in 3D printing, or in the case of material for molding or extrusion, fibers of a length of up to 12 mm and a range of slenderness between 40 and 70, preferably 10 mm in length and a slenderness range between 50-60.
    [0162]
    [0163] The preparation of part B may comprise, according to particular embodiments:
    [0164] - mixing the carboxymethylcellulose or the methylcellulose, or a combination of both with water, for example, in a blender at speeds such as 2,500 rpm for a time of, for example, one minute,
    [0165] - mixing the propyl, isopropyl, ethyl alcohol or combinations thereof and the weak acid, preferably acetic, for example, in a blender, for example one minute at speeds such as 2,500 rpm; the mixture can also be made manually in small quantities such as a volume of 1 liter, for 5 minutes.
    [0166] - add to the above mixture of alcohol and weak acid, the prepared mixture of CMC and water, and mix for example, in a blender, for example one minute at speeds such as 2,500 rpm
    [0167] - adding to all the above, the natural polysaccharide selected among the gums, and mixing, for example, in a blender, for example one minute at speeds such as 2,500 rpm, resulting in part B.
    [0168]
    [0169] According to particular embodiments of the process, the preparation of part A comprises
    [0170] - grind and grind the vegetable straw up to maximum specific granulometry of up to 5 millimeters, preferably a maximum of up to 3 mm, or in the case of material for molding or extrusion, up to obtaining fibers of a length of up to 12 mm and a maximum of slenderness between 40 and 70, preferably 10 mm in length and a range of slenderness between 50-60, obtaining 0.1-6.9% by weight of vegetable straw, so that the wood sawdust and vegetable straw add up as maximum 7% by weight,
    [0171] - selection of wood sawdust in a proportion of 0.1-6.9% by weight, with maximum specific granulometry of up to 3 millimeters, or in the case of material for molding or extrusion, select fibers with a maximum length of up to 12 mm and a slenderness range between 40 and 70, preferably 10 mm in length and a slenderness range between 50-60,
    [0172] - mixed vegetable straw and wood sawdust, in a blender, at 2,500 rpm, for 1 minute,
    [0173] - add 0.1-20% by weight of propyl, isopropyl, ethyl alcohol or combinations thereof to the mixture obtained above and mix, for example in a blender, at speeds depending on the amount of material, for example 2,500 rpm, during a time that depends on the amount of material, for example, 1 minute.
    [0174]
    [0175] According to particular embodiments of the process, the preparation of part B comprises:
    [0176] - mixing 0.1-25% by weight of carboxymethylcellulose (CMC), methylcellulose (MC) or a combination of both, with 0.1-45% by weight of water,
    [0177] - Mix 0.1-5% of propyl alcohol, isopropyl alcohol, ethyl alcohol or combinations thereof and 0.1-5% by weight of the weak acid,
    [0178] - add to the previous mixture of alcohol and weak acid, to the prepared mixture of CMC, MC or both, and water,
    [0179] - add to all of the foregoing, 0.1-12% by weight of natural polysaccharide, and mix, resulting in part B.
    [0180]
    [0181] According to further particular embodiments of the method, this comprises,
    [0182]
    [0183] - prepare a part A comprising:
    [0184] - crushing and milling vegetable straw up to specific particle sizes of up to 5 mm, preferably a maximum of up to 3 millimeters, or in the case of material for molding or extrusion, up to fibers up to a length of up to 12 mm and a range of slenderness between 40 and 70, preferably 10 mm in length and a slenderness range between 50-60, obtaining 0.1-17.9% by weight of vegetable straw, preferably rice straw, so that the wood sawdust and Vegetable straw account for a maximum of 18% by weight
    [0185] - selection of wood sawdust in a proportion of 0.1-17.9% by weight, with specific granulometries up to a maximum of 5 mm, preferably a maximum of up to 3 mm, or in the case of material for molding or extrusion, select fibers of a length of up to 12 mm and a slenderness range between 40 and 70, preferably 10 mm in length and a slenderness range between 50 60,
    [0186] - mixed vegetable straw and wood sawdust,
    [0187] - adding 0.1-20% by weight of propyl, isopropyl and / or ethyl alcohol to the mixture of vegetable straw, more preferably rice straw, and wood sawdust,
    [0188] - Preparation of part B comprising:
    [0189] - mixing 0.1-25% by weight of carboxymethylcellulose (CMC), methylcellulose (MC) or a combination of both, with 0.1-45% by weight of water,
    [0190] - mixing 0.1-5% by weight of propyl, isopropyl, ethyl alcohol or combinations thereof, with 0.1-5% by weight of the weak acid, more preferably still, acetic acid,
    [0191] - add to the previous mixture of alcohol and weak acid, the prepared mixture of CMC, MC or both, and water,
    [0192] - adding to the result of the previous step, 0.1-10% by weight of natural polysaccharide selected from the gums, more preferably still, gum arabic, and mixing, resulting in part B, and
    [0193] - mix part A and part B.
    [0194]
    [0195] The result of the mixture of CMC and water provides workability to the final material and a certain cohesion, which is further complemented with the addition of the natural polysaccharide.
    [0196]
    [0197] The weak acid, preferably acetic, acts as a biocide, and particularly as a natural insecticide and fungicide. As for alcohol, it provides greater workability to CMC without having to add more water.
    [0198]
    [0199] The material of the invention is susceptible to extrusion, molding by manual means or by additive application by 3D printing.
    [0200]
    [0201] In the case of 3D printing the granulometry is less than 135 microns, preferably less than 125 microns in the case of vegetable straw, preferably rice and for wood sawdust below 255 microns, preferably below 250 microns .
    [0202]
    [0203] The present invention also relates to the use of the material defined above in molding, extrusion or 3D printing processes.
    [0204]
    [0205] Particularly in the construction, the areas of application of the material of the invention can be the manufacture of artistic elements (such as sculptural elements or other ornamental elements), monuments falleros, materials for packaging, furniture, industrial articles, decorative articles and others.
    [0206]
    [0207] Example:
    [0208]
    [0209] A part A is prepared comprising:
    [0210] - grind and grind rice straw up to specific granulometries as maximum recommended up to 3 millimeters, obtaining 6% rice straw
    [0211] - selection of wood sawdust in a proportion of 12% by weight, with specific granulometries recommended up to a maximum of 3 millimeters,
    [0212] - mixing rice straw and wood sawdust, in a blender, at 2,500 rpm, for 1 minute,
    [0213] - add 10% by weight of isopropyl alcohol and / or ethyl alcohol to the mixture of rice straw and wood sawdust, mixing in a blender, at 2,500 rpm, for 1 minute;
    [0214] - Preparation of part B comprising:
    [0215] - mixing 17% by weight of carboxymethylcellulose with 45% by weight of water, at 2,500 rpm, for 1 minute,
    [0216] - mixing 1% by weight of isopropyl alcohol and / or ethyl alcohol with 3% by weight of acetic acid,
    [0217] - add to the previous mixture of alcohol and acetic acid, the prepared mixture of CMC and water, and mix in a blender, for one minute at speeds of 2,500 rpm - add to the result of the previous stage, 6% by weight of gum arabic , and mix, resulting in part B, and
    [0218] - mix part A and part B, for one minute at speeds of 2,500 rpm.
    权利要求:
    Claims (20)
    [1]
    1. A material for construction that includes:
    - at least between 0.1 and 6.9% by weight of vegetable straw,
    - 0.1-25% by weight of carboxymethylcellulose (CMC), methylcellulose (MC) or a combination of both,
    - 0.1-12% by weight of natural polysaccharide selected from the group consisting of D-galactose, L-arabinose, L-rhamnose, D-glucuronic acid, natural gums and combinations thereof, preferably gum arabic or gum tragacanth, - water , at least between 0.1 and 45% by weight,
    where all the percentages are percentages by weight with respect to the total weight of the construction material.
    [2]
    2. A construction material according to claim 1, further comprising the following components:
    - at least 0.1-6.9% by weight of wood sawdust, so that wood sawdust and vegetable straw account for a maximum of 7% by weight,
    - 0.1-25% by weight of propyl, isopropyl, ethyl alcohol, or combinations thereof, - 0.1-5% by weight of a weak acid.
    [3]
    3. A construction material according to claim 1 or 2, comprising:
    - 0.1-17.9% by weight of vegetable straw,
    - 0.1-25% by weight of carboxymethylcellulose (CMC), methylcellulose (MC) or a combination of both,
    0.1-12% by weight of natural polysaccharide selected from the group consisting of D-galactose, L-arabinose, L-rhamnose, D-glucuronic acid, natural gums and combinations thereof,
    - 0.1-17.9% by weight of wood sawdust, so that wood sawdust and vegetable straw account for a maximum of 18% by weight,
    - 0.1-25% by weight of propyl, isopropyl, ethyl alcohol, or combinations thereof
    0.1-5% by weight of a weak acid,
    - water between at least 0.1 and 45% by weight.
    where all the percentages are percentages by weight with respect to the total weight of the construction material.
    [4]
    4. A construction material according to any one of claims 2 or 3, wherein the vegetable straw and the wood sawdust are present in the following proportions:
    - 9-17.9% by weight of vegetable straw,
    - 0.1-9% by weight of wood sawdust, so that wood sawdust and vegetable straw account for a maximum of 18% by weight.
    [5]
    A construction material according to any one of claims 2 or 3, wherein the vegetable straw and the wood sawdust are present in the following proportions:
    - 4-6.9% by weight of vegetable straw,
    - 0.1-3% by weight of wood sawdust, so that wood sawdust and vegetable straw account for a maximum of 7% by weight.
    [6]
    6. A construction material according to any one of the preceding claims, wherein the vegetable straw is rice straw.
    [7]
    A construction material according to one of the preceding claims, in which the sawdust is wood sawdust selected from balsa wood, pine, poplar, willow, poplar, elm, cypress, spruce, cedar or high density oak, beech, chestnut, walnut, teak, olive, mahogany, cherry, ash and combinations of them.
    [8]
    A construction material according to one of the preceding claims, wherein the weak acid is selected from acetic, citric, boric, carbonic, phosphoric acid and combinations thereof.
    [9]
    9. A material for construction according to one of the preceding claims, comprising additives selected from air-entraining, fluidifying, flame retardant, flame diffusers, dyes and mixtures thereof.
    [10]
    10. A method for preparing the material for construction defined in one of the preceding claims, comprising:
    - grinding and milling the vegetable straw, obtaining a part A that comprises at least vegetable straw
    - preparation of a part B, comprising at least
    - carboxymethylcellulose, methylcellulose or a combination of both, in the proportions indicated in claim 1,
    - natural polysaccharide in the proportions indicated in claim 1 - water,
    in the proportions indicated in claim 1,
    where all the percentages are percentages by weight with respect to the total weight of the construction material and
    - mixing of part A and part B, resulting in the material of the invention ready for use.
    [11]
    11. A process according to claim 10, wherein the preparation of part A comprises:
    - crushing and grinding vegetable straw,
    - Selection of wood sawdust
    - mixed vegetable straw and wood sawdust.
    [12]
    12. A process according to claim 11, wherein the preparation of part A further comprises,
    - addition of 0.1-20% by weight of propyl, isopropyl, ethyl alcohol, or combinations thereof.
    [13]
    13. A method according to claim 10, wherein the preparation of part A comprises
    - grind and grind the vegetable straw up to specific granulometries of up to 3 millimeters maximum, or in the case of material for molding or extrusion until obtaining fibers up to 12 mm maximum and a slenderness range between 40 and 70, obtaining 0.1 -6.9% vegetable straw,
    - selection of wood sawdust in a proportion of 0.1-6.9% by weight, with specific granulometries of not more than 3 millimeters, or in the case of material for molding or extrusion select fibers with a maximum length of up to 12 mm and a range of slenderness between 40 and 70,
    - mixed vegetable straw and wood sawdust, in a blender, at 2,500 rpm, for 1 minute,
    - add 0.1-20% by weight of propyl, isopropyl, ethyl alcohol or combinations thereof to the mixture obtained above and mix.
    [14]
    14. A process according to claim 10, wherein the preparation of part B comprises:
    - mixing 0.1-25% by weight of carboxymethylcellulose, methylcellulose or a combination of both, with 0.1-45% by weight of water,
    - mixing 0.1-5% by weight of propyl, isopropyl, ethyl alcohol or combinations thereof and 0.1-5% by weight of the weak acid,
    - add to the previous mixture of alcohol and weak acid, the prepared mixture of CMC, MC or both, and water,
    - add to all of the foregoing, 0.1-12% by weight of natural polysaccharide, and mix, resulting in part B.
    [15]
    15. A method according to claim 10, comprising,
    - prepare a part A comprising:
    - grind and grind the vegetable straw up to specific granulometries of up to 3 millimeters maximum, or in the case of material for molding or extrusion until obtaining fibers up to 12 mm maximum and a slenderness range between 40 and 70, obtaining 0.1 -17.9% vegetable straw
    - selection of wood sawdust in a proportion of 0.1-6.9% by weight, with specific granulometries up to a maximum of 3 millimeters, or in the case of molding or extrusion material, select fibers with a maximum length of up to 12 mm and a slenderness range between 40 and 70,
    - mixed vegetable straw and wood sawdust,
    - adding 0.1-20% by weight of propyl, isopropyl, ethyl alcohol or combinations thereof, to the mixture of vegetable straw and wood sawdust, - preparation of part B comprising:
    - mixing 0.1-25% by weight of carboxymethylcellulose, methylcellulose or a combination of both, with 0.1-45% by weight of water,
    - mixing 0.1-5% by weight of propyl, isopropyl, ethyl alcohol or combinations thereof, with 0.1-5% by weight of the weak acid,
    - add to the previous mixture of alcohol and weak acid, the prepared mixture of CMC or MC and water,
    - adding to the result of the previous step 0.1-12% by weight of natural polysaccharide selected from the gums, and mixing, resulting in part B, and
    - mix part A and part B.
    [16]
    16. A process according to one of claims 10 to 15, wherein the vegetable straw is rice straw, the natural polysaccharide is gum arabic and the weak acid is acetic acid.
    [17]
    17. Use of the material defined in one of claims 1 to 9 in molding, extrusion or 3D printing processes.
    [18]
    18. Use of the material according to claim 17, in the manufacture of objects selected among artistic elements, objects for packaging, furniture, articles for industrial use and articles for decorative use.
    [19]
    19. Use of the material according to claim 18, in the manufacture of sculptures and ornaments.
    [20]
    20. Use of the material according to claim 19, wherein the sculptures are fallas monuments.
    类似技术:
    公开号 | 公开日 | 专利标题
    KR101360938B1|2014-02-21|Eco-friendly syntheitc wood composition including flame retardant and antimicrobial
    KR101187947B1|2012-10-05|Strength and fire-retardant reinforced eco-friendly synthetic wood products and method of eco-friendly synthetic wood
    US8716371B2|2014-05-06|Reed composite, manufacturing method thereof and building material using the same
    CN106589650A|2017-04-26|Fine-performance plastic material and preparation method thereof
    CN102531492B|2014-03-26|Cement-based wood fiber artificial board and manufacturing method thereof
    CN105906908A|2016-08-31|Degradable flame-retardant wood-plastic composite material and preparation method thereof
    CN108948575A|2018-12-07|A kind of Environmental protection floor material and preparation method thereof
    KR101180906B1|2012-09-07|Fiber Plastic Composite and Method for Manufacturing Thereof
    ES2703455A1|2019-03-08|MATERIAL FOR CONSTRUCTION BY MOLDING, EXTRUSION OR 3D PRINTING |
    CN102304280B|2012-12-26|Formaldehyde-free zero-carbon environmentally-friendly board synthetized by circuit board and manufacture technology thereof
    CN108911575A|2018-11-30|A kind of energy conservation and environmental protection novel floor material and preparation method thereof
    CN106553258B|2018-09-11|A kind of preparation process of formaldehydeless waterproof composite board
    Hermawan et al.2009|Manufacture of composite board using wood prunings and waste porcelain stone
    KR101882577B1|2018-07-26|An environment-friendly wall flooring material with ceramics
    CN104097246A|2014-10-15|Straw mixture artificial board and processing method
    KR100621225B1|2006-09-07|Synthetic woods and its manu- facturing methods
    WO2014207277A1|2014-12-31|Composition in an aqueous base, method for producing same, and use of said composition as a bioadhesive
    CN107828232A|2018-03-23|A kind of environmentally-friendly plastic sheet material and preparation method thereof
    CN104177731A|2014-12-03|Formula for producing construction template from PVC plastic
    CN107953439A|2018-04-24|A kind of fire retardant functionality plate prepared with culled wood and stalk waste residue
    CN103588427A|2014-02-19|Medium density fiberboard prepared by using geopolymer as cementing material
    CN111331703B|2022-02-11|Medium-density board and preparation method thereof
    KR102133562B1|2020-07-13|composition for synthetic wood and manufacturing method of synthetic wood using the same
    CN104231648A|2014-12-24|Environment-friendly reed board and preparation method thereof
    KR100933354B1|2009-12-22|Industrial rubber sheet containg plant and waste-rubber
    同族专利:
    公开号 | 公开日
    EP3459371A1|2019-03-27|
    WO2019048725A1|2019-03-14|
    ES2703455B2|2019-08-06|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US6768029B1|1999-06-18|2004-07-27|Cambridge Biopolymers Limited|Oxidative cleavage of unsaturated oils and products obtained therefrom|
    KR20080015035A|2008-01-16|2008-02-15|김남채|Insulation|
    WO2011130501A1|2010-04-16|2011-10-20|E2E Materials, Inc.|Naturally-sourced building materials|
    CN104692713A|2015-02-05|2015-06-10|安徽忠盛新型装饰材料有限公司|Waste porcelain powder composite environment-friendly decorative plate and preparation method thereof|
    US4071036A|1976-12-06|1978-01-31|Jacobs James D|Holder for elongate tobacco product|
    JPH0779759A|1993-09-13|1995-03-28|Setsuo Kuroki|Smoking tool provided with cigarette smoke-passing hole, front dilution mechanism and cigarette smoke flavor-impregnated member|
    CA2601538C|2005-03-17|2010-02-09|Japan Tobacco Inc.|Filter holder used for smoking, a smoking pipe, and a smoking pipe unit|
    GB2511303A|2013-02-27|2014-09-03|British American Tobacco Co|Smoking apparatus|
    法律状态:
    2019-03-08| BA2A| Patent application published|Ref document number: 2703455 Country of ref document: ES Kind code of ref document: A1 Effective date: 20190308 |
    2019-08-06| FG2A| Definitive protection|Ref document number: 2703455 Country of ref document: ES Kind code of ref document: B2 Effective date: 20190806 |
    优先权:
    申请号 | 申请日 | 专利标题
    ES201731095A|ES2703455B2|2017-09-21|2017-09-21|MATERIAL FOR CONSTRUCTION BY MOLDING, EXTRUSION OR 3D PRINTING|ES201731095A| ES2703455B2|2017-09-21|2017-09-21|MATERIAL FOR CONSTRUCTION BY MOLDING, EXTRUSION OR 3D PRINTING|
    EP18382400.2A| EP3459371A1|2017-09-21|2018-06-06|Cigarette mouthpiece|
    PCT/ES2018/070584| WO2019048725A1|2017-09-08|2018-09-05|Material for construction by molding, extrusion or 3d printing|
    [返回顶部]